Wachtershauser's Pop and Adapt



Here is Gunter Wachtershauser's 'Pop and Adapt' OOL scenario.
He first pops up metabolism which 'runs on its own' until it can adapt.
It has the same failings as all Pop and Adapt scenarios
(Pops out of nothing, no regard for the environment, has a magic cloak
to protect it from environmental damage until it can adapt to its environment,
and it does this for no other reason than we need it to happen to get to life)
Also note his "X taps of the chemical magic wand" that all these scenarios
also seem to have.

http://www.findarticles.com/p/articles/mi_m1200/is_2_155/ai_53630867

"... In Wachtershauser's theory, the first organic molecule
put together on the conveyor belt was acetic acid, a simple
combination of carbon, hydrogen, and oxygen that is best
known for giving vinegar its pungent odor. Formation of acetic
acid is a primary step in metabolism, the series of chemical
reactions that provides the energy that cells use to manufacture
all the biological ingredients an organism needs.

According to the theory, metabolism came before all else.
Once a primitive metabolism evolved, it began to run on its own,
and only later were cells' other basic elements, such as
a genetic code, invented.

Wachtershauser focuses on the heart of modern metabolism,
the citric acid cycle. All living cells use this series of
reactions to extract energy from food. The cycle makes
changes in several chemical compounds, but it always
begins with acetic acid. Inside a cell, the two carbon
atoms in each acetic acid molecule are eventually expelled
as carbon dioxide in a reaction that gives off a packet of energy.

Because the citric acid cycle is intrinsic to all modern life,
Wachtershauser guesses that its basic reactions are close
to the chemistry with which life began--with one significant
variation. In the oxygen-deficient world at hydrothermal vents,
heat-loving bacteria operate the cycle backward
(SN: 3/29/97, p. 192). Instead of giving off carbon dioxide
to make energy, they incorporate carbon atoms to build a
succession of more complex organic molecules. Wachtershauser s
ays life's first chemicals were built the same way.

Around the vents, he theorizes, catalytic metallic ions first
enabled the materials around them to fashion acetic acid.
In the next step, the ions catalyzed the addition of a
carbon molecule to the acetic acid to get three-carbon pyruvic acid,
which is another key chemical in the citric acid cycle and also
reacts with ammonia to form amino acids, which themselves
link up to form proteins.

.



Relevant Pages

  • Re: What else is there to drink?
    ... > It should be noted that acetic acid and phosphoric acid are NOT ... > drink much of either in the pure state. ... Vinegar is only a 5% solution of acetic acid in water. ...
    (sci.chem)
  • Re: When Geeks Cook
    ... Am I crazy but "aqueaous ethanolic acid" is somebody trying to be ... Ethanoic acid is the systematic name for the carboxylic acid associate ... trivial, name is acetic acid. ... you get vinegar. ...
    (soc.motss)
  • Re: Question regarding using epoxy or RTV on PCBs
    ... I just use whatever clear silicone is at the hardware store. ... do smell the acetic acid in silicone. ... Did you know you can make copper bright and shiney in vinegar? ... Vinegar has acetic acid.. ...
    (sci.electronics.design)
  • Re: NSAIDs - bad choice for osteoarthritis
    ... Lipid and cell metabolic changes associated with essential fatty acid ... enrichment of articular chondrocytes. ... Observations of impaired chondrocyte metabolism in essential fatty ...
    (sci.med.nutrition)
  • Re: CRP stimulates production of receptor for glycation end products (or elevated CRP and HbA1c toge
    ... Acetic acid ... It can donate its Acetic acid to proteins ... The proteins than become acetylated and unfunctional ... This does not happen with salicylic acid symply because salicylic acid ...
    (alt.support.diabetes)