Re: welcome to discuss the mechanism of cyclohexane oxidation



xiaoyong0610@xxxxxxxxxxxx wrote:
>
> Thanks for your information!
> But I think the mecanism different with H2O2 from that of using
> molecular oxygen as oxidant. I am not sure the initiate step should be
> catalyst act with H2O2 or cyclohexane act with H2O2. Which is initiate
> step?and how to show the mechanism?

Homolytic cleavage to hydroxyl then hydrogen abstraction, etc.

--
Uncle Al
http://www.mazepath.com/uncleal/
(Toxic URL! Unsafe for children and most mammals)
http://www.mazepath.com/uncleal/qz.pdf
.