Physical Interpretation of Negative pH.
- From: "Farooq W" <farooq.w@xxxxxxxxx>
- Date: 29 Aug 2005 08:09:43 -0700
Why are most general chemistry text simply silent on negative pH values
and values greater than 14? In the elementary classes chemistry
students learn that pH are defined from 0-14, but later they are unable
to accept the negative pH concept when by accident they _calculate_ pH
of > 1 M HCl, but of course activity comes into play.
(i) My question is what are common examples (leave aside super-acids)
of solutions having negative pH values and how are they experimentally
measured. Though I never tried, in fear of damaging it, but if I dip
the glass electrode in concentrated 12 M HCl would the pH-meter show
negative values?
(ii) Some people claim that the dissociation is controlled by self
ionization of water and the product [H+][OH-] = 10^-14 always holds
true.
See for example the answer 1 here:
http://www.newton.dep.anl.gov/askasci/chem99/chem99230.htm
(iii) A short note in J.Chem.Ed has a procedure for making a pH
-47 to +47 HCl solution which I think is meant to be a joke.
Suppose we have 1 liter of 1x10^-6 M HCl, add about 99 L of water, the
[HCl] is 1x10^-8 M and pH= 8. Now suppose you have single molecule of
HCl in 10^23 L of water, so that
[HCl] = 1.7x10^-47, the pH is then 47!
Regards,
Farooq.
.
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