Is it true that when you mix two volumes of identical gas, there is no entropy change?
- From: simondex@xxxxxxxxx
- Date: 27 Sep 2005 16:01:49 -0700
Hi, Everyone!
My textbook says that if two volumes of identical gas are mixed, there
is no change in entropy. Suppose I have vessel one (V1) and vessel 2
(V2). V1 and V2 are separated by a removable separator. V1 has 9
positions for molecules and has 2 molecules. V2 has 9 positions for
molecules and has 2 molecules. The number of molecular arrangements in
V1 is (9 choose 2) = 36. The same is true for V2. Thus my system, which
is composed of V1 and V2 has 36 * 36 = 1296 possible states. Suppose
the separator between V1 and V2 is removed. Gases diffuse. We now have
9+9 = 18 positions for molecules and 2+2 = 4 molecules in our system.
(18 choose 4) = 3060. Thus the entropy has increased. How come?
Thank You Very Much.
Truly Yours, Simon Dexter
.
- Follow-Ups:
- Prev by Date: Re: plastic lenses
- Next by Date: Re: Is it true that when you mix two volumes of identical gas, there is no entropy change?
- Previous by thread: Re: plastic lenses
- Next by thread: Re: Is it true that when you mix two volumes of identical gas, there is no entropy change?
- Index(es):