Re: removing ethanol from wine



"dave e" <dgenglish@xxxxxxxxxxx> wrote in message
news:1134931952.732455.301430@xxxxxxxxxxxxxxxxxxxxxxxxxxxxxxx
>
> N:dlzc D:aol T:com (dlzc) wrote:
>> Dear john:
>>
>> <john@xxxxxxxxxx> wrote in message
>> news:1134912495.288119.224550@xxxxxxxxxxxxxxxxxxxxxxxxxxxxxxx
>> >I want to remove ethanol from wine by heating it.
>>
>> Won't work.
>>
>
> Hold on there! The boiling point of pure ethanol is 78.3. The boiling
> point of the azeotropic mixture is 78.15. The boiling point of water
> is 100 C. If you heat the wine to a temperature anywhere above the the
> boiling temperature of pure ethanol (which is also above the boiling
> temperature of the azeotropic mixture) then your liquid phase should be
> essentially free of any alcohol. It certainly won't have enough
> alcohol in it to get anyone drunk.
>
> Your vapor phase, at and around 78.15, is only 95% ethanol.
>


Hold on. You won't get the azeotrope unless you have a good fractionating
column and the whole system is in equilibrium. Just do a phase diagram to
check if you want. If he starts with, say, 15% alcohol, then the distillate
will be somewhat enriched in ethanol, maybe around 20%. Most spirits are
distilled many times to get the concentration up to 40% as they don't use
columns. Thus the answer to remove all the ethanol from wine means boiling
it until about 80% has been boiled off.

--
--
Ron Jones

Don't repeat history, see unreported near misses in chemical lab/plant at
http://www.crhf.org.uk
Only two things are certain: The universe and human stupidity; and I'm not
certain about the universe.
~ Albert Einstein
>


.



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