Re: compare 2 samples
As Dave suggested, your data are highly non-normal. For non-negative times, the largest standard deviation relative to the mean occurs in the following extreme case.
N-1 measurements are zero and a single measurement is c (a constant). The mean is c/N and the standard deviation is c/sqrt(N). The ratio of the standard deviation to the mean is sqrt(N).
I suspect that in your data, the preponderance of the measurements are close to zero, with a very few being moderate or large.
Jack
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